He's on My Mind (2009)

Elementary school teacher, Kayla King thought she had the perfect relationship, and after an impromptu wedding, Kayla discovers that not only is she the other women...she's the other wife. Devastated, Kayla vows to figure out "WHY MEN DO WHAT THEY DO", and is spontaneously imbued with the ability to intercept men's thoughts. That's when the fun begins. Kayla newfound ability will present her with more than she bargained for, both in her personal life and at work.